煤炭工程 ›› 2017, Vol. 49 ›› Issue (6): 125-128.doi: 10.11799/ce201706036

• 研究探讨 • 上一篇    下一篇

基于衍射图谱低角度信息的煤化程度分析

王超1,余嘉栋2,李红3,张晓春4,王帅1   

  1. 1. 中国矿业大学现代分析与计算中心
    2. 中国矿业大学
    3. 中国矿业大学化工学院
    4. 中国矿业大学信电学院
  • 收稿日期:2016-11-14 修回日期:2017-01-14 出版日期:2017-06-09 发布日期:2017-06-20
  • 通讯作者: 余嘉栋 E-mail:yjd@cumt.edu.cn

Analysis of coalification degree based on low angle information of diffraction pattern

  • Received:2016-11-14 Revised:2017-01-14 Online:2017-06-09 Published:2017-06-20

摘要: 基于煤炭的衍射图谱,判断其煤化程度的常规方法是计算002峰峰高与半高宽的比值。探讨了九种不同变质程度煤的衍射图谱信息,在应用该方法进行煤化程度的比较分析后,认为该方法对中低变质程度煤的判定较为可靠,但对高阶煤有所欠缺。另外,通过布拉格方程计算,认为煤样衍射图谱低角度区(3°~10°)反映的是煤中直径为(0.884~2.94)nm的微孔信息,其衍射强度对应煤中的孔隙率。因此,结合孔隙率随煤化程度变化的规律,提出了一种全新的表征煤化程度的函数。新函数可综合煤样衍射图谱中的低角度区与002峰的信息,判定煤化程度。结果表明:该函数对于煤化程度的表征更加可行、可靠和精确。

关键词: X射线衍射图谱, 低角度信息, 孔隙率, 煤化程度

Abstract: According to the diffraction pattern of coal, the conventional method judging coalification degree is to calculate the ratio of the 002 peak height and FWHM. In this paper, the diffraction patterns of nine kinds of coal were sorted out and calculated. The results show that this method is more reliable for the judgment of medium and low metamorphic grade coal, but it is lacking for high rank coal. In addition, the low-angle region (3-10°) of the diffraction pattern of coal, which is calculated by Bragg equation, reflects the micropore information in the coal with a diameter of (0.884-2.94) nm, and its diffraction intensity corresponds to the porosity in coal. Therefore, the function of the coalification degree is defined according to the regulation of porosity variation with the coalification degree. It can be integrated coal information in the low-angle diffraction patterns and 002 peak to determine the degree of coalification. It is proved that this function is more feasible, reliable and accurate for characterization of coalification degree.

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